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The Man From U.N.C.L.E. Season 1 Episode 9

Solo and Illya devise a clever scheme to discredit a Balkan intelligence chief (Werner Klemperer) with a bogus secret gas. With the help of a bankrupt exterminator (William Shatner) and his wife, Illya poses as a fellow countryman and exploits the paranoia of the chief and his bumbling assistant (Leonard Nimoy).

Episode Title: The Project Strigas Affair

Air Date: 1964-11-24